Magnetic CoFe2O4@carbon yolk-shell nanoparticles as catalysts for the catalytic wet peroxide oxidation of paracetamol: kinetic insights

نویسندگان

چکیده

<p>This work focuses on the use of carbon-coated magnetic cobalt ferrite nanoparticles as catalysts for catalytic wet peroxide oxidation (CWPO) emerging concern pollutant paracetamol (PCM). The core catalyst is composed CoFe2O4 developed by a sol-gel method. subsequently coated with formaldehyde-resorcinol resin and TEOS, further carbonized at 600 ºC, etched NaOH to create yolk-shell structure denoted CoFe2O4@void@C. X-ray diffraction (XRD), transmission electron microscopy (TEM), Fourier transformed infra-red (FTIR) analysis revealed that uncoated cubic spinel crystallite size 53 nm calculated using Williamson-Hall (W-H) method, matching very well average observed TEM (53.51  4.2 nm). Comparing performances CoFe2O4@void@C bare in CWPO paracetamol, total organic carbon (TOC) removals 58% 46% are obtained respectively after 24 h reaction. An empirical kinetic model based second-order autocatalytic expressions was suitably describe decomposition H2O2 removal catalyst. disappearance TOC well-described (r2 = 0.98) lumped sum TOCA, TOCB TOCC, where TOCA PCM, refers intermediate products TOCC final during PCM.</p>

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Activated carbons treated with sulphuric acid: Catalysts for catalytic wet peroxide oxidation

Different liquid phase thermal treatmentswere applied to a commercial activated carbon (Norit ROX 0.8) in order to produce modified activated carbons with varying surface chemistry and increased acidic character. Chemical characterization of the prepared materials includes determination of the point of zero charge and evaluation of the concentration and nature of acidic and basic surface functi...

متن کامل

Bimetallic catalysts for continuous catalytic wet air oxidation of phenol.

Catalytic wet oxidation has proved to be effective at eliminating hazardous organic compounds, such as phenol, from waste waters. However, the lack of active long-life oxidation catalysts which can perform in aqueous phase is its main drawback. This study explores the ability of bimetallic supported catalysts to oxidize aqueous phenol solutions using air as oxidant. Combinations of 2% of CoO, F...

متن کامل

Degradation of paracetamol by catalytic wet air oxidation and sequential adsorption - Catalytic wet air oxidation on activated carbons.

The concern about the fate of pharmaceutical products has raised owing to the increasing contamination of rivers, lakes and groundwater. The aim of this paper is to evaluate two different processes for paracetamol removal. The catalytic wet air oxidation (CWAO) of paracetamol on activated carbon was investigated both as a water treatment technique using an autoclave reactor and as a regenerativ...

متن کامل

Catalytic Performance and Kinetic Study in the Total Oxidation of VOC over Micro/Meso Porous Catalysts

The total oxidation of toluene at a wide temperature range (200–500 oC) over micro/mesoporous platinated catalysts has been investigated about activity, selectivity to CO2 and CO, catalyst's stability versus coke deposition and reaction kinetics. Kinetic of toluene oxidation was measured under various oxygen and toluene pressures and als...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Global Nest Journal

سال: 2022

ISSN: ['1790-7632', '2241-777X']

DOI: https://doi.org/10.30955/gnj.004309